超声提取-离子色谱法测定银精矿中水溶性氟

银精矿中水溶性氟会随雨水的冲刷进入生物圈,直接对土壤、水体、大气、人类健康产生危害。实验提出超声提取-离子色谱法测定银精矿中水溶性氟,为银精矿中水溶性氟的检测及后续环境影响评估提供重要的技术支撑。称取0.2g样品(过150目筛),加入30mL水,在40℃时超声提取20min后,使用阴离子交换柱进行分离,使用碳酸钠-碳酸氢钠混合溶液作为淋洗液进行淋洗,洗脱时间为25min,通过电导检测器进行F^-检测。F^-质量浓度在0.5~10mg/L范围内与对应的峰面积呈线性关系,校准曲线线性相关系数为0.9998;方法检出限为0.062mg/L,测定下限为0.21mg/L。按照实验方法测定两个银精矿中水溶性氟,测定结果的相对标准偏差(RSD,n=6)为3.8%和4.3%;加标回收率为92%~102%。     

基于GF-1数据的三峡库区水体信息精细化提取

为实现江河类狭长型水体信息的精细化提取，利用GF-1卫星数据，采用支持向量机和目视解译相结合的方法对三峡库区及重庆市水体信息进行了精细化提取。使用总体分类精度、Kappa系数、错分误差、漏分误差、制图精度和用户精度等指标对库区水体信息粗提取结果进行验证分析。结果表明:4个试验区水体提取的总体分类精度均超过90%，除试验区4的Kappa系数为0.884 1以外，其余试验区均超过0.9，提取精度较高。结合目视解译的方法，在粗提取结果的基础上对各问题进行精细化处理，得到精度高、完整性好的三峡库区以及重庆市水体信息数据，可为后续该区域的精细化遥感业务开展提供有效资料。     

基于NB分类器重访概率预测的Web缓存替换策略

Web缓存是用来解决网络访问延迟和网络拥塞问题，缓存替换策略直接影响缓存的命中率。为此，提出一种朴素贝叶斯（NB）分类器重访概率预测的Web缓存替换策略；根据用户之前访问日志，通过分区操作提取多项特征来表示每次访问的对象，并构建特征数据集；训练NB分类器，用来确定缓存中对象被再次访问的概率，为对象分配权重；结合LRU策略来合理删除一些对象。仿真结果表明，提出的策略在保证较高命中率的同时有效降低了执行时间。     

Determining Stability Constants Using the AKUFVE Technique

ABSTRACT

The AKUFVE techniques were developed by Rydberg and co-workers in the 1960s. The main aim was to be able to perform a series of liquid-liquid extraction data varying one or more parameters and at the same time achieve very pure phases. As such, this technique was later used for short-lived isotope studies in the SISAK system, but also as a standalone unit for a large number of thermodynamic studies of extraction systems both for fundamental understanding as well as more applied investigations. In this paper, the apparatus with modifications made over the decades is described. In addition, studies with stability constant determinations for the zirconium-water-acetylacetone system as well as lanthanide extraction using bromodecanoic acid are exemplified to demonstrate the potential use of the technique. The results shown clearly demonstrate the versatility and ability of the AKUFVE system.     

浊点萃取在锕系和镧系元素分离分析中的应用

浊点萃取（cloud point extraction, CPE）是一种安全环保同时兼具高富集系数和低成本的萃取方法，在分析化学中已经被广泛应用于金属离子分析等领域。锕系和镧系金属元素存在环境复杂，自身浓度相对较低，对其进行分离和分析一直是放射化学研究者所关注的问题。经过条件优化，CPE能够有选择性地分离和富集锕系和镧系金属元素。通过与多种技术联用，CPE能实现锕系和镧系元素的高灵敏度分析。本文在介绍浊点萃取机理的基础上，着重描述了不同萃取体系中各类萃取剂（β-二酮类、膦氧类、含氮类、含硫类）对于锕系和镧系元素的萃取效果，全面总结了其中使用的不同联用技术，同时简述了通过构筑超分子识别位点，修饰配体，使用不同表面活性剂及掩蔽剂等改良现有浊点萃取体系的尝试。最后，对浊点萃取在放射化学领域的应用进行了总结和展望。     

Querying on large and complex databases by content: Challenges on variety and veracity regarding real applications

The amount and variety of digital data currently being generated, stored and analyzed, including images, videos, and time series, have brought challenges to data administrators, analysts and developers, who struggle to comply with the expectations of both data owners and end users. The majority of the applications demand searching complex data by taking advantage of queries that analyze different aspects of the data, and need the answers in a timely manner. Content-based similarity retrieval techniques are well-suited to handle large databases, because they enable performing queries and analyses using features automatically extracted from the data, without users’ intervention. In this paper, we review and discuss the challenges posed to the database and related communities in order to provide techniques and tools that can meet the variety and veracity characteristics of big and complex data, while also considering the aspects of semantical preservation and completeness of the data. Examples and results obtained over a two-decade-long experience with real applications are presented and discussed.     

Extraction equilibrium conditions of beryllium and aluminium from a beryl ore for optimal industrial beryllium compound production

This study examines the extraction of beryllium and aluminium from a Nigerian beryl ore using Cyanex®272 in kerosene from an aqueous sulphate pregnant solution. Parameters such as extractant concentration and equilibrium pH that dictates the extraction yield were studied. Under the following conditions: temperature 27?±?2°C, phase ratio 1?1, about 45.50 and 46.76% of beryllium and aluminium were extracted by 0.15?mol?L^?1 Cyanex®272 concentration within 30?min. However, the extraction yield of beryllium and aluminium was increased to 91.68% and 97.89% at equilibrium pH of 3 and 4, respectively, for beryllium and aluminium at 27?±?2°C. A 0.05?mol?L^?1 H₂SO₄ solution was found to be adequate for the stripping of about 99.00% Be and 95.40% Al from the loaded organic phase. The pure solutions containing metal ions were accordingly beneficiated to obtain beryllium and aluminium compounds of industrial values.